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Beilstein J. Org. Chem. 2015, 11, 2584–2590, doi:10.3762/bjoc.11.278
Graphical Abstract
Scheme 1: Schematic representation of ligands A and B.
Scheme 2: Synthesis of rhodium(I), iridium(I), and nickel(II) complexes of ligand B.
Scheme 3: Tolman electronic parameters (TEP) for A, B and their related monocarbenes.
Figure 1: CV plots of complexes 2 (a), and 3 (b). Experiments were carried out using 1 mM solutions of the co...
Figure 2: CV plot (a) and relevant DPV section (b) of complex 4. Experiments were carried out using 1 mM solu...
Scheme 4: Schematic representation of complex 6.